Pancake Bonding: An Unusual Pi‐Stacking Interaction
نویسندگان
چکیده
منابع مشابه
Intramolecular Pancake Bonding in Helical Structures.
We show that diradicaloid helical conjugated molecules can display strong through-space bonding interactions. These interactions are analogous to π-stacking pancake bonding widely observed for dimers and other aggregates of stable π-conjugated radicals. We show that these multicenter interactions can have a significant stabilizing effect, but they depend in subtle ways on the specific overlap a...
متن کاملPancake kidney: An unusual type of renal fusion anomaly found in 99mTc-DMSA renal scintigraphy
A 2.5-year-old boy with a history of the previous incidental finding of an ectopic kidney in ultrasonography was referred to our nuclear medicine center for 99mTc-DMSA renal scintigraphy. The scan showed an unusual type of ectopic fused kidneys on the right side of the lower abdomen. In this anomaly, kidneys were fused completely across the medial portion of both upper and lower pole...
متن کاملAn Experimental Investigation on the Pancake Problem
In this paper, we present an experimental investigation on the pancake problem. Also called sorting by prefix reversals (SBPR), this problem is linked to the genome rearrangement problem also called sorting by reversals (SBR). The pancake problem is a NP-hard problem. Until now, the best theoretical R-approximation was 2 with an algorithm which gives a 1.22 experimental R-approximation on stack...
متن کاملUnusual Bonding in Platinum Carbido Clusters.
Vibrational spectroscopy and density functional theory calculations are used to determine the structures of small gas-phase platinum carbido clusters PtnC(+), n = 3-5. The carbon atom is found to prefer three-coordinate binding sites near the center of the cluster, in contrast to most previously investigated adatoms on transition metal clusters. The Pt3C unit is particularly stable, and binding...
متن کاملKimura’s Disease – An Unusual Presentation
Introduction: Kimura’s disease is a rare chronic inflammatory disease of unknown etiology, presenting as painless subcutaneous nodules with lymphadenopathy and peripheral eosinophilia, mainly disturbing the head and neck region. It mainly affects Asian males in their 2nd to 4th decade of life. One such case of Kimura’s disease, which is uncommon in Indian natives, is reported. Case Report: A ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Chemistry – A European Journal
سال: 2018
ISSN: 0947-6539,1521-3765
DOI: 10.1002/chem.201802385